A Little More on Significant Figures (©2002, François G. Amar, All rights reserved)
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Here is some clarification on how Significant Figures work in calculations and a little more optional discussion for those who are interested.
Uncertainty in measurement
This is is governed by the nature of the
apparatus: a ruler marked in millimeters can really
only be trusted to give you one place to the right of the decimal as
in 8.9 cm because there are only
10 divisions per centimeter.
Uncertainty in derived results
We need to have some way of handling the
uncertainty that we propagate through a calculation
on the way to a derived result. We shall see that the
method of significant figures keeps us from
overestimating the information we have about a derived quantity. Now
suppose you have a scale which
allows you to measure with confidence masses between 0 and 100 grams
to a precision of 1/100th of
a gram. You would weigh out your compound using a container.
Subtracting the tare weight looks
like this:
(container + compound) 11.53 g
- container (empty) 9.31 g difference 2.22 g
We have let the number of significant figures that we report in
the answer take care of our uncertainty
limit. In this method we will not report ±
uncertainty
limits. The link to the left is OPTIONAL and
will
tell you more about uncertainty than many of you want to know.
Illustration of the addition rule for reporting the right
number of significant digits when adding two
numbers. An extreme example is the "battleship" problem. Can you
weigh a sailor by first weighing a
battleship empty and then weighing it with the sailor on board? No.
Why not? Let's suppose the battleship was in the 130,000 tonne class
(where tonne = metric ton = 1000 kg). This means the battleship
weighs
about 130 million kg = 1.3 x 108 kg. If we were to add the
mass of the sailor and expect to get a reasonable
estimate of her weight, we would have to be able to measure such a
large mass to a precision of at least 9
significant digits. No such measuring apparatus exists. The best we
might do is to get about 5 figures which might yield
mass of battleship = 131,530,000 kg <-- here no decimal point implies that the last 4 zeroes are not significant
The true mass might be anywhere from 131,525,000 to
131,534,990 kg. If the mass were less than
the first number, our apparatus would have "rounded down" to
131,520,000 kg and if the mass were
larger than the second number, our apparatus would have "rounded up"
to 131,540,000 kg. The range
of uncertainty in the true mass of the battleship is thus of the
order of the difference of these limits or
nearly 10,000 kg. Thus the mass of the sailor is only a small
fraction of the uncertainty in the mass of
the battleship.
The rule for addition is that you keep the
significant digits of the number with the least number of digits to
the right of the decimal point, thus:
1000.0 g <-- least number of
digits to right of decimal point
+ 31.5462 g
1031.5462
g --> must be rounded to
1031.5 g
Multiplication
The multiplication rule is easier to use but some
people seem to think it is less intuitive.
The rule is:
The answer in a multiplication or division has
the same number of significant digits as the number with the
least number of significant digits.
10.0 x 15343.1 = 153000 = 1.53x105 sig figs: 3 6 3
To understand this rule we need to remember how we learned
multiplication in grade school. All multiplication is really
addition. Let's suppose that the problem above is rewritten as a
grade school multiplication problem:
15343.1
x 10.0?
The question mark represents the fact the hundredths place or 4th
digit of the smaller number
is not known. Let's now work out this problem as we would in second
grade:
15343.1 <-- certain
to 6
digits
x 10.0?
<-- certain to 3
digits
???.???
0000.00
00000.0
153431.
adding
153???.???
<-- certain only to 3
digits
So the answer is 1.53 x 105 as above. The decimal point
(.) has gone to the
left of the
last 3 digits because the problem was set up with a total of 3 digits
to the right in the
"question" (.1 and .0?). [Note that wherever an uncertain digit
(?) multiplies a known
digit (like 3) we have an unknown result (?)].