Reading in Levine: Chapter 17.6 to 17.11
Homework problems
Hand in on Monday, February 2: 17.15, 17.21, 17.22, 17.23, 17.29, 17.31, 17.33, 17.39, 17.40, 17.41
Key Concepts
correspondence principle
operators
eigenfunctions and eigenvalues
postulates of quantum mechanics
square-integrability; expectation values
probability density
Key Equations
Classical to quantum correspondence
Particle in a 1-D box of length a:
V(x) = 0 for 0<x<a
V(x) = infinite for x≤0 or x≥a
Postulates of quantum mechanics:
1. The state of a system is described by a function (state function or wave function),
, which is a function of coordinates and time.
is single-valued, continuous, and quadratically integrable.
2. For each physical property (energy, momentum, angular momentum,...) of a system, there is an operator,
, which can be written down using the correspondence principle:
3. If the property
is measured, the only values that will be found are the eigenvalues of
as determined by the solutions of the eigenvalue equation:
.
4. The expectation value or average value of a property A is given by the integral:
5. The probability of finding a particle in a particular region of space (1-dimensional version) is:
.