(©2009, François G. Amar, All rights reserved)

Chemistry 475 -- Quantum Chemistry & Spectroscopy

Summary for Week 6&7

Monday, February 16 to Friday, February 27, 2009

Reading in Levine: Chapter 18

Homework problems

Hand in on Monday, February 23: 18.3, 18.15, 18.21, 18.22, 18.31, 18.35

Hand in on Friday, February 27:18.31, 18.35 and the the do-it-yourself portions of the

handouts on Angular Momentum, Commutators, and Electron Spin.

Hand in on Monday, March 16: perturbation theory problem from Handout

Key Concepts

kinetic energy operator is separable in spherical polar coordinates

hydrogen atom quantum numbers

orbital angular momentum and commutation relations

radial and angular wavefunctions

nodes of hydrogen atom wavefunctions

expectation values operators in hydrogenic atom states

commutators and simultaneous sets of eigenstates

simultaneous observables and the Heisenberg uncertainty principle

electron spin and angular momentum

Helium atom is a two-electron system; approximation methods.

Some Handouts

Hydrogen atom Hamiltonian (pdf)

Energy levels of the Hydrogen atom

Angular Momentum (pdf)

Commutators and Angular Momentum (pdf)

Electron Spin (pdf)

 

 

 

 

 

 

 

 

Back to Syllabus