(©2009, François G. Amar, All rights reserved)

Chemistry 475 -- Quantum Chemistry & Spectroscopy

Summary for Week 8&9

Monday, March 16 to Friday, March 27, 2009

Reading in Levine: Chapter 18

Homework problems on perturbation theory due on Monday, March 23

Key Concepts

Variation theory

Linear variation theory

Matrices and similarity transforms: symmetric and orthogonal matrices; hermitian and unitary matrices

Spin angular momentum and the helium atom.

Estimating the energy of the helium atom

Permutation symmetry: fermions and bosons

Determinantal wavefunction is antisymmetric

 

 

 

 

 

 

 

 

 

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